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1.
Entropy (Basel) ; 26(4)2024 Mar 29.
Artigo em Inglês | MEDLINE | ID: mdl-38667859

RESUMO

An entanglement-based continuous variable (CV) QKD scheme is proposed, performing information reconciliation over an entanglement-assisted link. The same entanglement generation source is used in both raw key transmission and information reconciliation. The entanglement generation source employs only low-cost devices operated in the C-band. The proposed CV-QKD scheme with information reconciliation over an entanglement-assisted link significantly outperforms the corresponding CV-QKD scheme with information reconciliation over an authenticated public channel. It also outperforms the CV-QKD scheme in which a classical free-space optical communication link is used to perform information reconciliation. An experimental demonstration over the free-space optical testbed established at the University of Arizona campus indicates that the proposed CV-QKD can operate in strong turbulence regimes. To improve the secret key rate performance further, adaptive optics is used.

2.
Adv Healthc Mater ; : e2303666, 2024 Mar 02.
Artigo em Inglês | MEDLINE | ID: mdl-38431774

RESUMO

Carbene-based bioadhesives have favourable attributes for tissue adhesion, including non-specific bonding to wet and dry tissues, but suffer from relatively weak fracture strength after photocuring. Light irradiation of carbene-precursor (diazirine) also creates inert side products that are absent under thermal activation. Herein, a dual activation method combines light irradiation at elevated temperatures for the evaluation of diazirine depletion and effects on cohesive properties. A customized photo/thermal-rheometer evaluates viscoelastic properties, correlated to the kinetics of carbene:diazoalkane ratios via 19 F NMR). The latter exploits the sensitive -CF3 functional group to determine joule-based light/temperature kinetics on trifluoroaryl diazirine consumption. The combination of heat and photoactivation produced bioadhesives that are 3× tougher compared to control. Dual thermal/light irradiation may be a strategy to improve viscoelastic dissipation and toughness of photo-activated adhesive resins.

3.
Biomater Sci ; 12(6): 1502-1514, 2024 Mar 12.
Artigo em Inglês | MEDLINE | ID: mdl-38284150

RESUMO

Bacteria migration at catheter insertion sites presents a serious complication (bacteraemia) with high mortality rates. One strategy to mediate bacteraemia is a physical barrier at the skin-catheter interface. Herein a colorimetric biosensor adhesive (CathoGlu) is designed and evaluated for both colorimetric detection of bacterial infection and application as a bacteria barrier. The design intent combines viscous, hydrophobic bioadhesive with an organic pH indicator (bromothymol blue). Visual observation can then distinguish healthy skin at pH = ∼5 from an infected catheter insertion site at pH = ∼8. The liquid-to-biorubber transition of CathoGlu formulation occurs via a brief exposure to UVA penlight, providing an elastic barrier to the skin flora. Leachates from CathoGlu demonstrate no genotoxic and skin sensitization effect, assessed by OECD-recommended in vitro and in chemico assays. The CathoGlu formulation was found non-inferior against clinically approved 2-octyl-cyanoacrylate (Dermabond™), and adhesive tape (Micropore™) within an in vivo porcine model. CathoGlu skin adhesive provides new opportunities to prevent sepsis in challenging clinical situations.


Assuntos
Bacteriemia , Cateterismo Periférico , Suínos , Animais , Cateteres de Demora , Pele
4.
Opt Express ; 31(24): 39765-39783, 2023 Nov 20.
Artigo em Inglês | MEDLINE | ID: mdl-38041292

RESUMO

The use of pre-shared entanglement in entanglement-assisted communication offers a superior alternative to classical communication, especially in the photon-starved regime and highly noisy environments. In this paper, we analyze the performance of several low-complexity receivers that use optical parametric amplifiers. The simulations demonstrate that receivers employing an entanglement-assisted scheme with phase-shift-keying modulation can outperform classical capacities. We present a 2x2 optical hybrid receiver for entanglement-assisted communication and show that it has a roughly 10% lower error probability compared to previously proposed optical parametric amplifier-based receivers for more than 10 modes. However, the capacity of the optical parametric amplifier-based receiver exceeds the Holevo capacity and the capacities of the optical phase conjugate receiver and 2x2 optical hybrid receiver in the case of a single mode. The numerical findings indicate that surpassing the Holevo and Homodyne capacities does not require a large number of signal-idler modes. Furthermore, we find that using unequal priors for BPSK provides roughly three times the information rate advantage over equal priors.

5.
Opt Express ; 31(24): 39906-39916, 2023 Nov 20.
Artigo em Inglês | MEDLINE | ID: mdl-38041303

RESUMO

To improve the reliability of entanglement-assisted (EA) communication over turbulent FSO channels we propose to perform the optical phase-conjugation on idler photons rather than turbulence affected signal photons and use adaptive optics. We experimentally demonstrate that reliable EA communication over outdoor 1.45 km FSO link, established at University of Arizona campus, is possible in strong turbulence regime.

6.
Opt Express ; 31(6): 10936-10946, 2023 Mar 13.
Artigo em Inglês | MEDLINE | ID: mdl-37157628

RESUMO

We evaluate the burst-error performance of the regular low-density parity-check (LDPC) code and the irregular LDPC code that has been considered for ITU-T's 50G-PON standard via experimental measurements in FPGA. By using intra codeword interleaving and parity-check matrix rearrangement, we demonstrate that the BER performance can be improved under ∼44-ns-duration burst errors for 50-Gb/s upstream signals.

7.
Phys Rev Lett ; 129(1): 010501, 2022 Jul 01.
Artigo em Inglês | MEDLINE | ID: mdl-35841545

RESUMO

The laws of quantum physics endow superior performance and security for information processing: quantum sensing harnesses nonclassical resources to enable measurement precision unmatched by classical sensing, whereas quantum cryptography aims to unconditionally protect the secrecy of the processed information. Here, we present the theory and experiment for entanglement-enhanced covert sensing, a paradigm that simultaneously offers high measurement precision and data integrity by concealing the probe signal in an ambient noise background so that the execution of the protocol is undetectable with a high probability. We show that entanglement offers a performance boost in estimating the imparted phase by a probed object, as compared to a classical protocol at the same covertness level. The implemented entanglement-enhanced covert sensing protocol operates close to the fundamental quantum limit by virtue of its near-optimum entanglement source and quantum receiver. Our work is expected to create ample opportunities for quantum information processing at unprecedented security and performance levels.

8.
Entropy (Basel) ; 24(7)2022 Jul 06.
Artigo em Inglês | MEDLINE | ID: mdl-35885158

RESUMO

The growth of data-driven technologies, 5G, and the Internet pose enormous pressure on underlying information infrastructure [...].

9.
Entropy (Basel) ; 24(7)2022 Jul 17.
Artigo em Inglês | MEDLINE | ID: mdl-35885213

RESUMO

Entanglement-based quantum sensors have much better sensitivity than corresponding classical sensors in a noisy and lossy regime. In our recent paper, we showed that the entanglement-assisted (EA) joint monostatic-bistatic quantum radar performs much better than conventional radars. Here, we propose an entanglement-assisted (EA) multistatic radar that significantly outperforms EA bistatic, coherent state-based quantum, and classical radars. The proposed EA multistatic radar employs multiple entangled transmitters performing transmit-side optical phase conjugation, multiple coherent detection-based receivers serving as EA detectors, and a joint detector.

10.
Entropy (Basel) ; 24(6)2022 May 26.
Artigo em Inglês | MEDLINE | ID: mdl-35741476

RESUMO

With the help of entanglement, we can build quantum sensors with sensitivity better than that of classical sensors. In this paper we propose an entanglement assisted (EA) joint monostatic-bistatic quantum radar scheme, which significantly outperforms corresponding conventional radars. The proposed joint monostatic-bistatic quantum radar is composed of two radars, one having both wideband entangled source and EA detector, and the second one with only an EA detector. The optical phase conjugation (OPC) is applied on the transmitter side, while classical coherent detection schemes are applied in both receivers. The joint monostatic-bistatic integrated EA transmitter is proposed suitable for implementation in LiNbO3 technology. The detection probability of the proposed EA joint target detection scheme outperforms significantly corresponding classical, coherent states-based quantum detection, and EA monostatic detection schemes. The proposed EA joint target detection scheme is evaluated by modelling the direct radar return and forward scattering channels as both lossy and noisy Bosonic channels, and assuming that the distribution of entanglement over idler channels is not perfect.

11.
Sensors (Basel) ; 22(5)2022 Feb 25.
Artigo em Inglês | MEDLINE | ID: mdl-35270961

RESUMO

The growing data demands are pushing researchers to pay more attention to spectrally efficient modulation formats. The four-dimensional (4D) signal constellation modulation format has been investigated for metro networks' applications to achieve better power efficiency. To cope with such modulation formats, the requirement of better digital signal processing (DSP) is also increasing rapidly. More complicated DSPs bring us extra costs; thus, the DSP-free coherent receivers are also investigated because of the high-power consumption of conventional DSP-based receivers, but the transceivers upgrading also results in extra costs. In this invited paper we implement a 4-dimentional modulation format based on Slepian sequences. We applied LDPC coding and experimentally investigated the BER performance in a two-dimensional (2D) 40 km fiber link transmission and demonstrate that being error free is possible without employing the complicated DSP. We compared our proposed modulation scheme with regular 16QAM and found it outperforms 16QAM with DSP over back-to-back transmission by 3.8 dB improvement in OSNR when BER = 10-5, while over 40 km metro network communication link our proposed 4D modulation signals are still successfully transmitted, and the LDPC-coding still works properly with such a new transmission strategy. On the other hand, DSP-free transmission of LDPC-coded 16-QAM exhibits an early error floor phenomenon.

12.
Entropy (Basel) ; 23(8)2021 Jul 25.
Artigo em Inglês | MEDLINE | ID: mdl-34441090

RESUMO

Traditionally, the study of quantum key distribution (QKD) assumes an omnipotent eavesdropper that is only limited by the laws of physics. However, this is not the case for specific application scenarios such as the QKD over a free-space link. In this invited paper, we introduce the geometrical optics restricted eavesdropping model for secret key distillation security analysis and apply to a few scenarios common in satellite-to-satellite applications.

13.
Entropy (Basel) ; 23(8)2021 Jul 31.
Artigo em Inglês | MEDLINE | ID: mdl-34441143

RESUMO

Quantum key distribution (QKD) assures the theoretical information security from the physical layer by safely distributing true random numbers to the communication parties as secret keys while assuming an omnipotent eavesdropper (Eve). In recent years, with the growing applications of QKD in realistic channels such as satellite-based free-space communications, certain conditions such as the unlimited power collection ability of Eve become too strict for security analysis. Thus, in this invited paper, we give a brief overview of the quantum key distribution with a geometrical optics restricted power collection ability of Eve with its potential applications.

14.
ACS Appl Mater Interfaces ; 13(31): 36839-36848, 2021 Aug 11.
Artigo em Inglês | MEDLINE | ID: mdl-34342218

RESUMO

Carbene-based macromolecules are an emerging new stimuli-sensitive class of biomaterials that avoid the impediments of free radical polymerization but maintain a rapid liquid-to-biorubber transition. Activation of diazirine-grafted polycaprolactone polyol (CaproGlu) is limited to UVA wavelengths that have tissue exposure constraints and limited light intensities. For the first time, UVA is circumvented with visible light-emitting diodes at 445 nm (blue) to rapidly activate diazirine-to-carbene covalent cross-linking. Iridium photocatalysts serve to initiate diazirine, despite having little to no absorption at 445 nm. CaproGlu's liquid organic matrix dissolves the photocatalyst with no solvents required, creating a light transparent matrix. Considerable differences in cross-linking chemistry are observed in UVA vs visible/photocatalyst formulations. Empirical analysis and theoretical calculations reveal a more efficient conversion of diazirine directly to carbene with no diazoalkane intermediate detected. Photorheometry results demonstrate a correlation between shear moduli, joules light dose, and the lower limits of photocatalyst concentration required for the liquid-to-biorubber transition. Adhesion strength on ex vivo hydrated tissues exceeds that of cyanoacrylates, with a fixation strength of up to 20 kg·f·cm2. Preliminary toxicity assessment on leachates and materials directly in contact with mammalian fibroblast cells displays no signs of fibroblast cytotoxicity.


Assuntos
Adesivos/química , Materiais Biocompatíveis/química , Complexos de Coordenação/química , Diazometano/análogos & derivados , Animais , Catálise/efeitos da radiação , Colágeno/química , Complexos de Coordenação/efeitos da radiação , Complexos de Coordenação/toxicidade , Reagentes de Ligações Cruzadas/química , Irídio/química , Irídio/efeitos da radiação , Irídio/toxicidade , Luz , Camundongos , Células NIH 3T3 , Poliésteres/química , Suínos
15.
ACS Biomater Sci Eng ; 7(9): 4463-4473, 2021 09 13.
Artigo em Inglês | MEDLINE | ID: mdl-34387486

RESUMO

Bone fractures are in need of rapid fixation methods, but the current strategies are limited to metal pins and screws, which necessitate secondary surgeries upon removal. New techniques are sought to avoid surgical revisions, while maintaining or improving the fixation speed. Herein, a method of bone fixation is proposed with transparent biopolymers anchored in place via light-activated biocomposites based on expanding CaproGlu bioadhesives. The transparent biopolymers serve as a UV light guide for the activation of CaproGlu biocomposites, which results in evolution of molecular nitrogen (from diazirine photolysis), simultaneously expanding the covalently cross-linked matrix. Osseointegration additives of hydroxyapatite or Bioglass 45S5 yield a biocomposite matrix with increased stiffness and pullout strength. The structure-property relationships of UV joules dose, pin diameter, and biocomposite additives are assessed with respect to the apparent viscosity, shear modulus, spatiotemporal pin curing, and lap-shear adhesion. Finally, a model system is proposed based on ex vivo investigation with bone tissue for the exploration and optimization of UV-active transparent biopolymer fixation.


Assuntos
Pinos Ortopédicos , Fraturas Ósseas , Diazometano , Durapatita , Fraturas Ósseas/cirurgia , Humanos
16.
Entropy (Basel) ; 23(6)2021 Jun 01.
Artigo em Inglês | MEDLINE | ID: mdl-34206138

RESUMO

The measures of information transfer which correspond to non-additive entropies have intensively been studied in previous decades. The majority of the work includes the ones belonging to the Sharma-Mittal entropy class, such as the Rényi, the Tsallis, the Landsberg-Vedral and the Gaussian entropies. All of the considerations follow the same approach, mimicking some of the various and mutually equivalent definitions of Shannon information measures, and the information transfer is quantified by an appropriately defined measure of mutual information, while the maximal information transfer is considered as a generalized channel capacity. However, all of the previous approaches fail to satisfy at least one of the ineluctable properties which a measure of (maximal) information transfer should satisfy, leading to counterintuitive conclusions and predicting nonphysical behavior even in the case of very simple communication channels. This paper fills the gap by proposing two parameter measures named the α-q-mutual information and the α-q-capacity. In addition to standard Shannon approaches, special cases of these measures include the α-mutual information and the α-capacity, which are well established in the information theory literature as measures of additive Rényi information transfer, while the cases of the Tsallis, the Landsberg-Vedral and the Gaussian entropies can also be accessed by special choices of the parameters α and q. It is shown that, unlike the previous definition, the α-q-mutual information and the α-q-capacity satisfy the set of properties, which are stated as axioms, by which they reduce to zero in the case of totally destructive channels and to the (maximal) input Sharma-Mittal entropy in the case of perfect transmission, which is consistent with the maximum likelihood detection error. In addition, they are non-negative and less than or equal to the input and the output Sharma-Mittal entropies, in general. Thus, unlike the previous approaches, the proposed (maximal) information transfer measures do not manifest nonphysical behaviors such as sub-capacitance or super-capacitance, which could qualify them as appropriate measures of the Sharma-Mittal information transfer.

17.
Mater Sci Eng C Mater Biol Appl ; 127: 112240, 2021 Aug.
Artigo em Inglês | MEDLINE | ID: mdl-34225880

RESUMO

Stimuli-sensitive biomaterials that are activated by light are in need of formulations that are stable under indoor lighting yet can be activated under direct sunlight. Carbene-based bioadhesives are a new generation of film-forming polymers that are stable under indoor lighting yet are rapidly activated with low-energy UVA light, but have never been evaluated under sunlight exposure. Previous investigations have evolved two flexible carbene-based platforms, where aryl-diazirine is grafted on to polyamidoamine dendrimers (PAMAM-NH2; generation-5) or hydrophobic liquid polycaprolactone tetrol to yield G5-Dzx and CaproGlu, respectively. For the first time the activation of G5-Dzx and CaproGlu is investigated by natural sunlight with intensities up to 10 mW·cm-2. Structure-property relationships of bioadhesion are investigated by: (1) joules dose of sunlight; (2) bioadhesive polymer structure; and (3) optical concentrators of magnifying glass and Fresnel lens. Using only natural sunlight, adhesion strength could be tuned from 20 to 150 kPa with crosslinking achieved in under 1 min. The results show that carbene-based polymers are a class of stimuli-sensitive biomaterials that are stable to indoor lighting, yet can be rapidly activated under direct sunlight, which may be useful for topical film forming polymers or as active ingredients in sunscreen formulations.


Assuntos
Adesivos , Luz Solar , Materiais Biocompatíveis , Diazometano , Polímeros
18.
Opt Express ; 28(25): 37129-37148, 2020 Dec 07.
Artigo em Inglês | MEDLINE | ID: mdl-33379553

RESUMO

Conventionally, unconditional information security has been studied by quantum cryptography although the assumption of an omnipotent eavesdropper is too strict for some realistic implementations. In this paper, we study the realistic secret key distillation over a satellite-to-satellite free space optics channel where we assume a limited-sized aperture eavesdropper (Eve) in the same plane of the legitimate receiver (Bob) and determine the secret key rate (SKR) lower bounds correspondingly. We first study the input power dependency without assumptions on Bob's detection scheme before optimizing the input power to determine lower bounds as functions of transmission distances, center frequency or Eve aperture radius. Then we calculate analytical expressions regarding the SKR lower bound and upper bound as transmission distance goes to infinity. We also incorporate specific discrete variable (DV) and continuous variable (CV) protocols for comparison. We demonstrate that significantly higher SKR lower bounds can be achieved compared to traditional unrestricted Eve scenario.

19.
Entropy (Basel) ; 22(8)2020 Jul 29.
Artigo em Inglês | MEDLINE | ID: mdl-33286602

RESUMO

Research in quantum communications networks (QCNs), where multiple users desire to generate or transmit common quantum-secured information, is still in its beginning stage. To solve for the problems of both discrete variable- and continuous variable-quantum key distribution (QKD) schemes in a simultaneous manner as well as to enable the next generation of quantum communication networking, in this Special Issue paper we describe a scenario where disconnected terrestrial QCNs are coupled through low Earth orbit (LEO) satellite quantum network forming heterogeneous satellite-terrestrial QCN. The proposed heterogeneous QCN is based on the cluster state approach and can be used for numerous applications, including: (i) to teleport arbitrary quantum states between any two nodes in the QCN; (ii) to enable the next generation of cyber security systems; (iii) to enable distributed quantum computing; and (iv) to enable the next generation of quantum sensing networks. The proposed QCNs will be robust against various channel impairments over heterogeneous links. Moreover, the proposed QCNs will provide an unprecedented security level for 5G+/6G wireless networks, Internet of Things (IoT), optical networks, and autonomous vehicles, to mention a few.

20.
Entropy (Basel) ; 22(9)2020 Sep 22.
Artigo em Inglês | MEDLINE | ID: mdl-33286829

RESUMO

In this paper, we propose the surface codes (SCs)-based multipartite quantum communication networks (QCNs). We describe an approach that enables us to simultaneously entangle multiple nodes in an arbitrary network topology based on the SCs. We also describe how to extend the transmission distance between arbitrary two nodes by using the SCs. The numerical results indicate that transmission distance between nodes can be extended to beyond 1000 km by employing simple syndrome decoding. Finally, we describe how to operate the proposed QCN by employing the software-defined networking (SDN) concept.

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